Welcome the Technical Support section. Help us in assisting you by providing us with a concise and descriptive elaboration of your issues. Be specific and if possible, provide us with a step-by-step instruction in replicating your problem.
This can be done by re-ordering countries in the countries.xml file located in /components/com_community/libraries/fields/ directory
Just move United States to the top of the list. It's a simple cut & paste operation.
source
Currently the list is alphabetically ordered
you can overrides the template:
copy profile.php
from [Joomla Root]/components/com_community/templates/jomsocial/layouts/register/
to [Joomla Root]/templates/[frontend template]/html/com_community/layouts/register/